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By J. P. Singh, Narottam P. Bansal, Balakrishnan G. Nair, Tatsuki Ohji, Antonio R. de Arellano Lopez

This court cases contains papers awarded on the cutting edge Processing and Synthesis of Ceramics, Glasses and Composites symposium. issues contain powders, movies, coatings, fibers, composites, and functionally graded fabrics; sol-gel, polymer precursor, and gentle chemistry options; novel processing and microstructure-property relationships; response forming, combustion synthesis, and CVD; oxidation of metals and mechanical alloying; electrophoresis and plasma processing; and mechanism and kinetics of processes.Content:

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ACKOWLEDGEMENT This work was supported by the GROWTH program of the Commission of the European Communities under project contract No. G5RD-CT2000-00354, by the Fund for Scientific Research Flanders under project No. Leuven under project GOA/2005/08-TBA. O. J. Vandeperre, "Electrophoretic deposition of materials" Annual Review of Materials Science, 29,327-352 (1999). 2 P. S. Nicholson and X. Huang, "Zirconia-Alumina Functionally Graded Composites by Electrophoretic Deposition Techniques",/ Am. Ceram.

The potential of this system follows from the properties of AI2O3 (low wear rate, high hardness) and Zr02 (high strength, high toughness). Due to the difference in thermal expansion coefficient of AI2O3 and Z1O2, residual stresses are also developed during cooling down from the sintering temperature, which strongly influences the mechanical properties like strength and toughness7,8. Innovative Processing and Synthesis of Ceramics, Glasses and Composites IX 45 THE KINETICS DURING EPD For the deposition of FGM materials, coatings and laminated materials, it is essential to have a description of the deposition yield during EPD in order to fully control the deposition process.

6, together with the predicted composition profile. From this figure, it is clear that there is a good correlation between the experimentally measured and predicted gradient. 100 90 ~ o ^ o ex < ■■■■■■■■■ 80 \ 70 60 / ■ ■■■■'••»»•■ ■■■■¥■*'■"•¥ ■ 50 Measured cone, profile Predicted cone profile 40 1 2 3 Distance (mm) 4 5 Fig. 6. Measured and predicted FGM profile of AI2O3 / Z1O2 FGM disk. The model and method we have presented here to control the EPD process in order to produce a predetermined composition profile differs from the method we used earlier3'4.

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