By D. William Tedder, Frederick G. Pohland
Rising applied sciences for unsafe Waste administration VII: an summary; F.G.Pohland, D.W. Tedder.Chemical and Thermal Methods: Granular Iron Oxide as a Catalyst in Chemical Oxidation of natural Contaminants; M.D. Gurol, et al. An Electron Beam Generated Plasma Reactor for Decomposition of Halogenated VOCs; S.A. Vitale, et al. Incineration and Thermal remedy of Chemical brokers and Chemical guns; F.C.Gouldin, E.M. Fisher.Biochemical Treatment: Anaerobic changes of Carbon Tetrachloride: mixed micro organism and Abiotic strategies; F.W.Picardal, et al. Biorecovery of Metals from Acid Mine Drainage; R.Govind, et al.Separation Technologies: The removing of VOCs from Exhaust Air and Vapor Condensates by means of Membrane approaches; H. Chmiel, etal. Electrochemical restoration of EDA and Heavy Metals from Washing of steel infected Soil; S.B. Martin, et al. elimination and remedy of Radioactive, Organochlorine, and Heavy steel Contaminants from sturdy Surfaces; S.A. Grieco, et al. Electrolytic Decontamination of Conductive fabrics for harmful Waste administration; D.E. Wedman, etal. 7 extra Articles. Index.
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Extra info for Emerging Technologies in Hazardous Waste Management 7
C. Gouldln and E. M. Fisher INCINERATION CHEMISTRY In spite of the obvious need for it, relatively little is known about the chemical mechanisms controlling CWA destruction. Extensive measurements of trace species emissions have been made during CWA incineration tests at Johnston Atoll [1 I], but they have focused on the products of incomplete combustion typically observed during combustion and the incineration of industrial wastes such as chlorinated solvents. Byproducts specific to CWA incineration may have been overlooked in the absence either of extensive· incineration experience with these classes of compounds or of an understanding of their mechanisms of destruction.
52. Tapscott, R. , Moore, T. , Kaizerman, J. , Kibert, C. , and Tetla, R. , Advanced Agent Halon Substitutes, 1995 International CFC and Halon Alternatives Conference Washington, DC (1995). 53. ,J. Phys. Chem. 95: 2988--2994 (1991). 54. Cool, T. , Cornell University, personal communication (1995). 55. Korobeinichev, O. , Chernov, A. , and Shvartsberg, V. , Destruction Chemistry of Trimethyl phosphate in H2/02/Ar Flame Studied by Molecular Beam Mass-Spectrometry, 3rd Asia-Pacific International Symposium on Combustion and Energy Utilization (1995).
For toluene decomposition, the leaving group either a hydrogen from the methyl group, or the entire methyl group. For Freon 113 decomposition, the leaving group is probably a chlorine atom. The bond energy of the different bonds in toluene and Freon 113 are given in Table II. The bond energy represents the theoretical minimum amount of energy that must be imparted to the molecules by a collision with an electron in order for dissociation to occur. The actual electron energy required for decomposition will be higher than this minimum level, since the molecule must be excited into a quantized electron energy state by the collision.